Download e-book for kindle: Adhesion Aspects of Polymeric Coatings by K.L. Mittal

By K.L. Mittal

ISBN-10: 1461336600

ISBN-13: 9781461336600

This quantity chronicles the court cases of the Symposium on Adhesion elements of Polymeric Coatings held lower than the auspices of the Electrochemical Society in Minneapolis, MN, may possibly 10-15, 1981. This occasion was once cosponsored through the Dielectric and Insulation, and Electrothermics and Metallurgy Divisions. Polymeric coatings are used for a couple of reasons, e. g. , ornamental, protecting, useful (as dielectrics or insulators) and a distinct program of polymeric (organic) coatings is their use as lithographic fabrics for making built-in circuit components. regardless of the aim of the coating, it needs to adhere good to the underlying substrate. So the necessity to less than­ stand the standards which impact adhesion of natural coatings and the how one can reach wanted adhesion is sort of appear. This Symposium was once designed to assemble scientists and technologists drawn to the adhesion points of polymeric coatings, to supply a discussion board for dialogue of contemporary findings, and to supply a chance for cross-pollination of principles. The technical software contained a complete of forty six papers by means of authors from quite a few corners of the area. this system comprised either invited overviews and contributed unique examine papers, as this combination is easy methods to current the nation of data of a subject. The invited audio system have been chosen on the way to signify broadly fluctuate­ ing disciplines and pursuits they usually hailed from a number of aca­ demic and commercial study laboratories.

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Additional resources for Adhesion Aspects of Polymeric Coatings

Example text

The Raman line due to the propyl chain was used as an internal standard. B. Silanes on Substrates 1. Factors Affecting the Silane Interphase The factors that influence the structure of the coupling agent layers and subsequently the mechanical and physical properties of composites are the structure of the silane in the treating solution, the organofunctionality of the silane, the drying conditions, the topology of the reinforcement, and the chemical composition of the surface. Thus, it is essential to study the relationship between these factors and the structure of the silane interface.

Kinetics of Pore Penetration The discussion above assumes that equilibrium contact between liquid adhesive or coating and rough substrate is achieved. However adhesives set in what may be quite a short time, and so may never reach equilibrium contact. It is therefore relevant to consider the kinetics of penetration of the adhesive. The starting point for such a discussion is usually Poiseuille's Law 16 for the flow rate dx/dr of a Newtonian liquid of viscosity n Table I. S mJ/m 2 . 4 31 82 98 ROLE OF SURFACE TOPOGRAPHY 23 in a tube of radius r under the influence of a pressure P: dx x dt = rZp Bn (6) If the driving pressure is taken to be the capillary pressure Equation (6) may be integrated, assuming 6 and n are constant to give the Washburn equation 17 which shows the penetration Xt is proportional to the square root of time: xZ = t rYLVcos6 Zn t (7) Good 6 has pointed out that if the walls of the capillary immediately ahead of the penetrating liquid are free from absorbed vapor of the liquid, an additional force associated with the spreading pressure will draw the liquid into the tube and Equation (7) should be modified accordingly: (8) If some adsorption has occurred but not reached equilibrium, penetration will be intermediate between the values predicted by Equation (7) and Equation (8).

Al. 57 to occur by dissolving away the aluminum substrate and its anodic oxide with sodium hydroxide solution and examining the "underside" of the polyethylene in the scanning electron microscopy, Figure 4. When freed from the oxide the individual polymer fibers corne together in "clumps" a micron or so in width. Adhesion increased with thickness of the anodic film for films formed at the same voltage in the same electrolyte, Figure 5. Thicker films resulting from longer anodizing times would be likely to show more belling out of the pores at the surface.

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Adhesion Aspects of Polymeric Coatings by K.L. Mittal


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